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Questions of the form:

An electron and a positron collide with E MeV of energy, what is the frequency of the photons released.

quite often come up in my A Level course (for often fairly arbitrary E). But this got me thinking. There is energy stored in the separation of an electron and a positron, which, as they get closer and closer together, should all be converted into kinetic energy. As the potential is of the form $frac{1}{r}$, this implies that at arbitrarily small distances and arbitrarily high amount of energy is given off. Given that both electrons and positrons are typically regarded as point particles, in order for them to collide, they would have to be arbitrarily close together, which would imply that over the course of their collision they should have released arbitrarily high amounts of energy, in the form of kinetic energy. As this would imply photons of arbitrarily high frequency given off, I assume that I must have missed out some piece of physics somewhere, but I am uncertain where. Ideas I have had so far include:

• Energy should be given off, anyway, by an accelerating electron, in the form of light, according to classical EM, although I don't know how this changes from classical to quantum ideas of EM - we certainly can't have all the energy given off in a continuous stream, because we need quantised photons, so does the electron itself experience quantised energy levels as it accelerates inwards (my only issue with treating the electron in such a quantised way is that, to my mind, it'd be equivalent of treating it mathematically as a hydrogen-like atom, where the probability of the electron colliding with the positron is still extremely low, and unlike electron capture, there'd be no weak force interaction to mediate this 'electron-positron atom').


• The actual mechanism for the decay occurs at a non-zero separation distance, perhaps photons pass between the two particles to mediate the decay at non-infinitesimal distances.


• At relativistic speeds our classical model of electrodynamics breaks down. Now, I know this to be true - considering the fact that magnetism is basically the relativistic component of electrodynamics. However, given the fact that magnetism is the only relativistic force which'd be involved, I don't see how it'd act to counteract this infinite release of energy - so is there another force which I'm forgetting?

These are just ideas I've come up with whilst thinking about the problem, and I don't know if any of them have any physical significance in this problem, so any advice is appreciated!

This is a great question! It can be answered on many different levels.

You are absolutely right that if we stick to the level of classical high school physics, something doesn't make sense here. However, we can get an approximately correct picture by "pasting" together a classical and a quantum description. To do this, let's think of when the classical picture breaks down.

In relativistic quantum field theory, particles can only be localized on the scale of their Compton wavelength
$$lambda = frac{hbar}{mc}.$$
This means that the classical picture of point particles must break down as we approach this separation distance. Now, the electric potential energy released at this point is
$$E = frac{e^2}{r} = frac{e^2 m c}{hbar}$$
in cgs units. Here one of the most important constants in physics has appeared, the fine structure constant which characterizes the strength of electromagnetism,
$$alpha = frac{e^2}{hbar c} approx frac{1}{137}.$$
The energy released up to this point is
$$E approx alpha m c^2$$
which is not infinite, but rather only a small fraction of the total energy.

Past this radius we should use quantum mechanics, which renders the $1/r$ potential totally unapplicable -- not only do the electrons not have definite positions, but the electromagnetic field doesn't even have a definite value. Actually thinking about the full quantum state of the system at this point is so hairy that not even graduate-level textbooks do it; they usually black-box the process and only think about the final results, just like your high school course is doing. Using the full theory of quantum electrodynamics, one can show the most probable final outcome is to have two energetic photons come out. In high school you just assume this happens and use conservation laws to describe the photons long after the process is over.

For separations much greater than $lambda$, the classical picture should be applicable, and we can think of part of the energy as being released as classical electromagnetic radiation, which occurs generally when charges accelerate. (At the quantum level, the number of photons released is infinite, indicating a so-called infrared divergence, but they are individually very low in energy, and their total energy is perfectly finite.) As you expected, this energy is lost before the black-boxed quantum process starts, so the answers in your school books are actually off by around $1/137$. But this is a small enough number we don't worry much about it.

Positronium is what you're describing in your first idea.

Until/unless a believable model of the electron is developed, pretty much the best we can do is say that the rest mass of the electron-positron system is the only energy available to be converted to radiation in an annihilation event.

This experiment will reveal a lot more about what happens in very close encounters between electrons and positrons.

Your whole question is based on the idea that the potential energy stored by separation would convert to infinite kinetic energy. But this premise is wrong.

This requires that potential energy to be infinite. However, the potential energy is finite even when two charged particles are at infinite separation.

Potential is definitely not in the form of $frac{1}{r}$. If it were, that would mean the potential would increase as the particles are closing in. That is not the case.